Propagation and termination steps in Rh-mediated carbene polymerisation using diazomethane
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چکیده
منابع مشابه
Propagation and termination steps in Rh-mediated carbene polymerisation using diazomethane.
Rh-mediated carbene (co)polymerisation of diazomethane works best in the presence of Rh(III) catalyst precursors, the use of which leads to a significant increase in polymer yield and molecular weight. Chain termination via β-hydride elimination is severely suppressed for these species, although this process does still occur leading to unsaturated chain ends. Subsequent chain walking leading to...
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ژورنال
عنوان ژورنال: Dalton Transactions
سال: 2013
ISSN: 1477-9226,1477-9234
DOI: 10.1039/c2dt32584e